In the context of structural plastics, the use of reinforced polymers has gained increasing importance in the past few decades in several manufacturing sectors. In particular, thermosetting carbon-fiber reinforced composites (CFRCs) have recently become leading contenders in a large number of industrial applications where lightness represents an asset, including transportation (automotive, aerospace), construction (building and infrastructures, wind turbines) and consumer/sporting goods.
With growing amounts of CFRCs being used worldwide, the corresponding waste materials, including manufacturing off-cuts, scraps and end-of-life (EoL) components, are slowly but steadily reaching significant levels. This scenario has raised environmental and economic awareness on the need for sustainable routes for CFRC waste management and valorization, also in view of the high economic value of CFRCs on a global scale. At present, CFRC waste management is typically based on landfill disposal or incineration. However, the economic costs of such approaches are becoming increasingly high. In addition, major environmental concerns have led to strict management conditions with respect to composite waste, especially in the EU (e.g., directives 1999/31/EC and 2000/53/EC). As a result, the definition of a correct waste management strategy accomplishing the transition from a linear to a circular economy represents an impelling issue for both business and environment.
Within this framework, recent progresses in organic and polymer chemistry offer innovative pathways that may help to improve CFRC EoL and waste management through the incorporation of intrinsic de/remanufacturing functionalities in CFRCs at the material design and production stage. In particular, the use of dynamic crosslinking bonds in the macromolecular network of thermosetting materials has been recently introduced as powerful chemical tool to equip thermosets with new thermally-triggered functionalities potentially enabling their repairing, welding, reprocessing and reuse. While several examples of such dynamic systems have been demonstrated based on different types of chemistries, the use of such thermally-responsive thermosets in the field of CFRCs has been surprisingly limited, with only a few works directly related to long carbon fiber reclamation or matrix recovery, with these two issues being typically addressed separately. As a result, a holistic approach to treat CFRC waste in its integrity (repair, de/remanufacturing and reuse of CFRC part, full recovery of both CFs and thermosetting matrix) is still lacking, especially within the framework of economically sound and environmentally sustainable circular economy business models.